% % Herein I define some safety advices which I had to include with my % lab protocols in organic chemistry. % The latest version will be made available at % http://projects.thiemo.net/RundS/ % and distributed via CTAN % % % Copyright (c) 1997-2005 Thiemo Nordenholz % All rights reserved. % $Id: eng_rs.tex,v 1.6 2005/12/01 12:21:21 thiemo Exp $ % % Redistribution and use in source and binary forms, with or without % modification, are permitted provided that the following conditions % are met: % 1. Redistributions of source code must retain the above copyright % notice, this list of conditions and the following disclaimer. % 2. Redistributions in binary form must reproduce the above copyright % notice, this list of conditions and the following disclaimer in the % documentation and/or other materials provided with the distribution. % % THIS SOFTWARE IS PROVIDED BY THE AUTHOR AND CONTRIBUTORS ``AS IS'' AND % ANY EXPRESS OR IMPLIED WARRANTIES, INCLUDING, BUT NOT LIMITED TO, THE % IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE % ARE DISCLAIMED. IN NO EVENT SHALL THE AUTHOR OR CONTRIBUTORS BE LIABLE % FOR ANY DIRECT, INDIRECT, INCIDENTAL, SPECIAL, EXEMPLARY, OR CONSEQUENTIAL % DAMAGES (INCLUDING, BUT NOT LIMITED TO, PROCUREMENT OF SUBSTITUTE GOODS % OR SERVICES; LOSS OF USE, DATA, OR PROFITS; OR BUSINESS INTERRUPTION) % HOWEVER CAUSED AND ON ANY THEORY OF LIABILITY, WHETHER IN CONTRACT, STRICT % LIABILITY, OR TORT (INCLUDING NEGLIGENCE OR OTHERWISE) ARISING IN ANY WAY % OUT OF THE USE OF THIS SOFTWARE, EVEN IF ADVISED OF THE POSSIBILITY OF % SUCH DAMAGE. % % \message{Package 'eng_rs', 01.12.2005 (v1.3i), nz@thiemo.net} % numbers are coded o, e, z, d, v, f, s, i, a, n % combinations are prefixed with an extra-'c', % for information and examples see README. % define some 'R'-phrases: % R1-9 \def\cre{R1 Explosive when dry.} \def\crz{R2 Risk of explosion by shock, friction, fire or other sources of ignition.} \def\crd{R3 Extreme risk of explosion by shock, friction, fire or other sources of ignition.} \def\crv{R4 Forms very sensitive explosive metallic compounds.} \def\crf{R5 Heating may cause an explosion.} \def\crs{R6 Explosive with or without contact with air.} \def\cri{R7 May cause a fire.} \def\cra{R8 Contact with combustible material may cause fire.} \def\crn{R9 Explosive when mixed with combustible material.} % R10-19 \def\creo{R10 Flammable.} \def\cree{R11 Highly flammable.} \def\crez{R12 Extremely flammable.} \def\cred{R13 Extremely flammable liquefied gas.} \def\crev{R14 Reacts violently with water.} \def\cref{R15 Contact with water liberates highly flammable gases.} \def\cres{R16 Explosive when mixed with oxidizing substances.} \def\crei{R17 Spontaneously flammable in air.} \def\crea{R18 In use, may form flammable/explosive vapour-air mixture.} \def\cren{R19 May form explosive peroxides.} % R20-29 \def\crzo{R20 Harmful by inhalation.} \def\crze{R21 Harmful in contact with skin.} \def\crzz{R22 Harmful if swallowed.} \def\crzd{R23 Toxic by inhalation.} \def\crzv{R24 Toxic in contact with skin.} \def\crzf{R25 Toxic if swallowed.} \def\crzs{R26 Very toxic by inhalation.} \def\crzi{R27 Very toxic in contact with skin.} \def\crza{R28 Very toxic if swallowed.} \def\crzn{R29 Contact with water liberates toxic gas.} % R30-39 \def\crdo{R30 Can become highly flammable in use.} \def\crde{R31 Contact with acids liberates toxic gas.} \def\crdz{R32 Contact with acids liberates very toxic gas.} \def\crdd{R33 Danger of cumulative effects.} \def\crdv{R34 Causes burns.} \def\crdf{R35 Causes severe burns.} \def\crds{R36 Irritating to eyes.} \def\crdi{R37 Irritating to respiratory system.} \def\crda{R38 Irritating to skin.} \def\crdn{R39 Danger of very serious irreversible effects.} % R40-48 \def\crvo{R40 Possible risks of irreversible effects.} \def\crve{R41 Risk of serious damage to eyes.} \def\crvz{R42 May cause sensitization by inhalation.} \def\crvd{R43 May cause sensitization by skin contact.} \def\crvv{R44 Risk of explosion if heated under confinement.} \def\crvf{R45 May cause cancer.} \def\crvs{R46 May cause heritable genetic damage.} \def\crvi{R47 May cause birth defects.} \def\crva{R48 Danger of serious damage to health by prolonged exposure.} \def\crvn{R49 May cause cancer by inhalation.} \def\crfo{R50 Very toxic to aquatic organisms.} \def\crfe{R51 Toxic to aquatic organisms.} \def\crfz{R52 Harmful to aquatic organisms.} \def\crfd{R53 May cause long-term adverse effects in the aquatic environment.} \def\crfv{R54 Toxic to flora.} \def\crff{R55 Toxic to fauna.} \def\crfs{R56 Toxic to soil organisms.} \def\crfi{R57 Toxic to bees.} \def\crfa{R58 May cause long-term adverse effects in the environment.} \def\crfn{R59 Dangerous for the ozone layer.} % ***********Don't know the translations to the following************** % * If anyone knows, please mail me * % \def\crso{R60 Kann die Fortpflanzungsf"ahigkeit beeintr"achtigen.} % \def\crse{R61 Kann das Kind im Mutterleib sch"adigen.} % \def\crsz{R62 Kann m"oglicherweise die Fortpflanzungsf"ahigkeit % beeintr"achtigen} % \def\crsd{R63 Kann das Kind im Mutterleib m"oglicherweise sch"adigen.} % \def\crsv{R64 Kann S"auglinge "uber die Muttermilch sch"adigen.} % ********************************************************************** % Combinations of R-phrases \def\crcevef{R14/15 Reacts violently with water, liberating highly flammable gases.} \def\crcefzn{R15/29 Contact with water liberates toxic, highly flammable gas.} \def\crczoze{R20/21 Harmful by inhalation and in contact with skin.} \def\crczozz{R20/22 Harmful by inhalation and if swallowed.} \def\crczozezz{R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.} \def\crczdzv{R23/24 Toxic by inhalation and in contact with skin.} \def\crczvzf{R24/25 Toxic in contact with skin and if swallowed.} \def\crczdzf{R23/25 Toxic by inhalation and if swallowed.} \def\crczdzvzf{R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.} \def\crczszi{R26/27 Very toxic by inhalation and in contact with skin.} \def\crcziza{R27/28 Very toxic in contact with skin and if swallowed.} \def\crczsza{R26/28 Very toxic by inhalation and if swallowed.} \def\crczsziza{R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.} \def\crcdsdi{R36/37 Irritating to eyes and respiratory system.} \def\crcdida{R37/38 Irritating to respiratory system and skin.} \def\crcdsda{R36/38 Irritating to eyes and skin.} \def\crcdsdida{R36/37/38 Irritating to eyes, respiratory system and skin.} \def\crcvzvd{R42/43 May cause sensitization by inhalation and skin contact.} % % also some 'S-phrases' % S1-9 \def\cse{S1 Keep locked up.} \def\csz{S2 Keep out of reach of children.} % unfortunately, the following is not 'Keep cool' ;-) \def\csd{S3 Keep in a cool place.} \def\csv{S4 Keep away from living quarters.} \def\csf#1{S5 Keep contents under #1 .} \def\css#1{S6 Keep contents under #1 .} \def\csi{S7 Keep container tightly closed.} \def\csa{S8 Keep container dry.} \def\csn{S9 Keep container in a well-ventilated place.} % S10-19 \def\cseo{S10 Keep contents wet.} \def\csee{S11 Avoid contact with air.} \def\csez{S12 Do not keep the container sealed.} \def\csed{S13 Keep away from food, drink and animal feeding stuffs.} \def\csev#1{S14 Keep away from #1 .} \def\csef{S15 Keep away from heat.} \def\cses{S16 Keep away from sources of ignition - No smoking.} \def\csei{S17 Keep away from combustible material.} \def\csea{S18 Handle and open container with care.} % S20-29 \def\cszo{S20 When using do not eat or drink.} \def\csze{S21 When using do not somoke.} \def\cszz{S22 Do not breathe dust.} \def\cszd{S23 Do not breathe gas/fumes/vapour/spray.} \def\cszv{S24 Avoid contact with skin.} \def\cszf{S25 Avoid contact with eyes.} \def\cszs{S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice.} \def\cszi{S27 Take off immediately all contaminated clothing.} \def\csza#1{S28 After contact with skin wash immediately with plenty of #1 .} \def\cszn{S29 Do not empty into drains.} % S30-39 \def\csdo{S30 Never add water to this product.} \def\csde{S31 Keep away from explosive materials.} \def\csdd{S33 Take precautionary measures against static discharges.} \def\csdv{S34 Avoid shock and friction.} \def\csdf{S35 This material and its container must be disposed of in a safe way.} \def\csds{S36 Wear suitable protective clothing.} \def\csdi{S37 Wear suitable gloves.} \def\csda{S38 In case of insufficient ventilation wear suitable respiratory equipment.} \def\csdn{S39 Wear eye/face protection.} % S40-49 \def\csvo#1{S40 To clean the floor and all objects contaminated by this material use #1 .} \def\csve{S41 In case of fire and/or explosion do not breathe fumes.} \def\csvz{S42 During fumigation/spraying wear suitable respiratory equipment.} \def\csvd#1{S43 In case of fire use #1 .} \def\csvv{S44 If you feel unwell seek medical advice (show the label where possible).} \def\csvf{S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).} \def\csvs{S46 If swallowed seek medical advice immediately and show this container or label.} \def\csvi#1{S47 Keep at temperature not exceeding #1$^\mathrm{o}$C.} \def\csva#1{S48 Keep wetted with #1 .} \def\csvn{S49 Keep only in the original container.} % S50-59 \def\csfo#1{S50 Do not mix with #1 .} \def\csfe{S51 Use only in well-ventilated areas.} \def\csfz{S52 Not recommended for interior use on large surface areas.} \def\csfd{S53 Avoid exposure - obtain special instructions before use.} \def\csfv{S54 Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.} \def\csff{S55 Treat using the best available techniques before discharge into drains or the aquatic environment.} \def\csfs{S56 Do not discharge into drains or the environment; dispose to an authorised waste collection point.} \def\csfi{S57 Use appropriate containment to avoid environmental contamination.} \def\csfa{S58 To be disposed of as hazardous waste.} \def\csfn{S59 Refer to manufacturer/supplier for information on recovery/recycling.} \def\csso{S60 This material and/or its container must be disposed of as hazardous waste.} % Kombinationen der S-Saetze. \def\cscez{S1/2 Keep locked up and out of reach of children.} \def\cscsa{S7/8 Keep container tightly closed and dry.} \def\cscdsn{S3/7/9 Keep container tightly closed in a cool, well-ventilated place.} \def\cscdn{S3/9 Keep in a cool, well-ventilated place.} \def\cscdev#1{S3/14 Keep in a cool place away from #1 .} \def\cscdnev#1{S3/9/14 Keep in a cool, well-ventilated place away from #1 .} \def\cscdnvn{S3/9/49 Keep only in the original container in a cool, well-ventilated place.} \def\cscdnevvn#1{S3/9/14/49 Keep only in the original container in a cool, well-ventilated place away from #1 .} \def\cscia{S7/8 Keep container tightly closed and dry.} \def\cscin{S7/9 Keep container tightly closed and in a well-ventilated place.} \def\csczoze{S20/21 When using do not eat drink or smoke.} \def\csczvzf{S24/25 Avoid contact with skin and eyes.} \def\cscdsdi{S36/37 Wear suitable protective clothing and gloves.} \def\cscdsdn{S36/39 Wear suitable protective clothing and eye/face protection.} \def\cscdidn{S37/39 Wear suitable gloves and eye/face protection.} \def\cscdsdidn{S37/38/39 Wear suitable gloves, respiratory equipment and eye/face protection.} \def\cscvivn#1{S47/49 Keep only in the original container at temperature not exceeding #1$^\mathrm{o}$C.} % -- Pooh! got it :)