% !TEX TS-program = pdflatexmk
% Template file for TeXShop by Michael Sharpe, LPPL
\documentclass[12pt]{article}
\usepackage[margin=1in]{geometry} 
\usepackage[parfill]{parskip}% Begin paragraphs with an empty line rather than an indent
\usepackage{graphicx}
\pdfmapfile{=libertinust1math.map}
%SetFonts
% libertine+newtxmath
\usepackage[sb]{libertine} % use sb in place of bold
\usepackage[T1]{fontenc}
\usepackage{textcomp}
\makeatletter
\def\LinuxLibertine@scale{1.2}
\makeatother
\usepackage[varqu,varl]{zi4}% inconsolata
\usepackage{amsmath,amsthm}
\usepackage[]{libertinust1math}
%\usepackage[noamssymbols]{newtxmath}
% option vvarbb gives you stix blackboard bold
\useosf % use oldstyle figures except in math
\usepackage[cal=boondoxo]{mathalfa}% less slanted than STIX cal
%SetFonts
\usepackage{booktabs}
\pagestyle{empty}
\begin{document}
%\expandafter\meaning\csname mathsfbfit \endcsname
{\tt Options=[]}, and no use of \verb|\mathsfxxxx| macros.\\

$y=f(x)$.
%\verb|\mathsf{x}+\mathsfbf{y}+\mathsfbfit{z}+\mathsfit(w)|}
%\[\mathsf{x}\quad+\]
%\quad\mathsfbf{y}\quad+\quad\mathsfbfit{z}\quad\text{$\backslash$mathsfit is undefined}\]


\ShowMathFonts
%+\quad\mathsfit{w}\]
\end{document}  
*** Mathgroups ***
(0: \LS1/libertinust1math/m/n/12 = libertinust1-mathrm at 14.39996pt [operators])
(1: \LS1/libertinust1math/m/it/12 = libertinust1-mathit at 14.39996pt [letters])
(2: \LS2/libertinust1mathsym/m/n/12 = libertinust1-mathsym at 14.39996pt [symbols])
(3: \LS2/libertinust1mathex/m/n/12 = libertinust1-mathex at 14.39996pt [largesymbols])
(4: \LS1/libertinust1mathbb/m/n/12 = libertinust1-mathbb at 14.39996pt [symbolsbb])
(5: \LS1/libertinust1math/b/n/12 = libertinust1-mathrm-bold at 14.39996pt [bold-operators])
(6: \LS1/libertinust1math/b/it/12 = libertinust1-mathit-bold at 14.39996pt [bold-letters])